The character XML settings are only ever changed after you modify a window property in game, therefore if your window is not UserResizable there is no possibility that your size settings in the character xml will update.
Possible solutions include to make the window resizable (possibly with a maximum size) or to have it set its intended size OnShow.
This "problem" is also one of the reasons that you should never use the same uisettings with different UIs.
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