Strange. Maybe your newly bought potions have a different ID number. Sometimes SOE changes them, that's when you can't stack the items although they have the same name.
This potion is currently configured:
\aITEM 771875864 -1321989687:Expert's Noxious Remedy\/a
You can check yours by linking it (drag it to a chat window), marking the link and copying it somewhere out of game (Ctrl-C to copy, Ctrl-V to paste).
I don't see another possibility of what might be wrong right now... If your link code is different, please post it here.
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