First, until your DarqUI settings are loading and saving properly, I would configure just one icon for testing. When that icon is working, then you can safely configure the rest of them. Log in to the game and change one Icon Bar icon. Click each Save button that appears.
Next, in the utility on the Files page, click Open in File Explorer. Double-click the POI folder and find darquiv3_iconbar.xml. Right-click, go to Properties and make a note of the Modified Date. Now go back to the POI_Origins folder and look at the same file. Which of the two has a Modified Date from just a few moments ago?
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