O_o what's that?
 

Unknown Error: mscorlib
at System.IO.__Error.WinIOError(Int32 errorCode, String str)
at System.IO.FileStream..ctor(String path, FileMode mode, FileAccess access, FileShare share, Int32 bufferSize, Boolean useAsync, String msgPath, Boolean bFromProxy)
at System.IO.FileStream..ctor(String path, FileMode mode)
at WindowsApplication7.Form1.GetFileMD5(String FilePath)
at WindowsApplication7.Form1.DownloadExtras()
at WindowsApplication7.Form1.DoUpdates()
at WindowsApplication7.Form1.Timer3_Tick(Object sender, EventArgs e)
at System.Windows.Forms.Timer.OnTick(EventArgs e)
at System.Windows.Forms.Timer.Callback(IntPtr hWnd, Int32 msg, IntPtr idEvent, IntPtr dwTime)Access to the path "C:\Program Files\Sony\EverQuest II RU\UI\Super\images\maps\map_adv03_village.dds" is denied.

Looks like your .NET settings don't allow the application to access the C:\ drive files. Are you running EQ2Map from the C drive or a different one?